Soon after, on 28 September 1868 she married the Duke of Alençon, son of Louis d'Orléans, at Possenhofen Castle near Starnberg.
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After the marriage of her older sister, Duchess Mathilde Ludovika in Bavaria to 1861 to the Neapolitan Prince Luis of the Two Sicilies, her parents then looked for a suitable husband for Sophie Charlotte.
Duchess Sophie Charlotte in Bavaria (1847–1897), Duchess of Alençon and born Duchess in Bavaria
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